📚 Wiki Antimicrobial & Immune LL-37

LL-37

◎ Phase II (wound healing, lung infections)
Cathelicidin Antimicrobial Peptide (hCAP-18/LL-37)
Also known as: Cathelicidin, hCAP-18 C-terminal, CAMP peptide, Human cathelicidin antimicrobial peptide
Brand names: LL-37 (research grade), Cathelicidin LL-37
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Quick Summary

LL-37 is the only human cathelicidin, the C-terminal 37-amino acid fragment of the precursor protein hCAP-18, cleaved by proteases at sites of infection and inflammation. It is produced primarily by neutrophils, epithelial cells, and keratinocytes as part of the innate immune response.

Immune & Antimicrobial Extensively Studied
LL-37 is the only human cathelicidin, the C-terminal 37-amino acid fragment of the precursor protein hCAP-18, cleaved by proteases at sites of infection and inflammation. It is produced primarily by neutrophils, epithelial cells, and keratinocytes as part of the innate immune response. LL-37 has direct antimicrobial activity against bacteria, viruses, and fungi, while simultaneously modulating inflammation, promoting wound healing, and supporting angiogenesis. Its broad biological activity makes it a research target for wound care, respiratory infections, and skin conditions.
Storage Stability
Lyophilized
1–2 years (-20°C)
Reconstituted
~30 days (2–8°C)
Room temp
Avoid

Mechanism of Action

LL-37 acts through membrane disruption of pathogens and receptor-mediated immunomodulation of host cells.

Antimicrobial Membrane Disruption

LL-37 has an amphipathic alpha-helical structure that inserts into bacterial membranes, disrupting membrane integrity and causing osmotic lysis. It is effective against gram-positive bacteria (Staphylococcus, Streptococcus), gram-negative bacteria (Pseudomonas, E. coli), and many fungi. Importantly, it retains activity against antibiotic-resistant strains including MRSA.[1]

Toll-Like Receptor Modulation

LL-37 binds and modulates TLR2, TLR4, and TLR9, blocking excessive LPS-driven inflammation while maintaining appropriate pathogen sensing. This immunomodulatory activity reduces sepsis-associated cytokine storm while preserving antimicrobial defense, a therapeutically favorable balance.[2]

Wound Healing and Angiogenesis

LL-37 promotes keratinocyte and fibroblast migration through activation of EGFR and FPRL1 receptors. It stimulates VEGF expression, promoting angiogenesis in wound beds. These pro-healing effects make it relevant for chronic non-healing wounds, diabetic ulcers, and post-surgical repair.[3]

Research Overview

Wound Healing and Skin Repair

Strong Evidence

LL-37 accelerates re-epithelialization in wound models by promoting keratinocyte migration and proliferation. In diabetic wound models, LL-37 restores the impaired innate immune response at the wound site, reducing bacterial burden while promoting closure. Phase II evaluation in chronic wounds has been conducted.[3]

Antimicrobial Activity

Strong Evidence

LL-37 broad-spectrum antimicrobial activity covers 90%+ of clinical pathogen strains tested in vitro. Activity against biofilm-forming organisms (Pseudomonas in cystic fibrosis lungs, Staphylococcus in wound infections) is particularly clinically relevant as biofilms resist conventional antibiotics.[1]

Respiratory Infections and Lung Protection

Phase II Clinical

Aerosolized LL-37 has been evaluated in Phase II trials for lung infections in cystic fibrosis and ventilator-associated pneumonia. Reduced bacterial counts and improved inflammatory markers observed. LL-37 deficiency in vitamin D-deficient populations is associated with increased respiratory infection susceptibility.[2]

Psoriasis and Autoimmune Relevance

Moderate Evidence

LL-37 plays a paradoxical role in psoriasis, at high skin concentrations it triggers the autoimmune cascade by forming immunogenic complexes with self-DNA. Blocking LL-37 signaling is being explored as a psoriasis treatment. Understanding this dual role is important for therapeutic application.[4]


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Research Protocols

GoalDoseFrequencyRoute
Wound healing100–200 µgOnce dailySC near wound or topical
Immune support50–100 µgOnce dailySubcutaneous
Respiratory / intranasal50–100 µg1–2× dailyIntranasal

No specific meal timing required. Topical application is appropriate for skin wounds. SC administration for systemic immune support. Very short plasma half-life means local effects are primary; consider twice-daily dosing for sustained antimicrobial protocols.

Research protocols only. Not medical advice.


Peptide Interactions

synergistic
BPC-157 provides mucosal protection and repair signaling; LL-37 adds antimicrobial activity. Powerful combination for gut infection or wound care protocols.
compatible
GHK-Cu adds collagen remodeling to LL-37 wound healing effects. Common wound care combination.
compatible
TA1 adaptive immune enhancement complements LL-37 innate antimicrobial activity for comprehensive immune support.

Safety Profile

LL-37 safety profile is favorable at research doses. It is an endogenous human peptide.

Psoriasis caution: Elevated LL-37 is a trigger in psoriasis pathogenesis. Avoid in active psoriasis or confirmed psoriatic autoimmunity.

Local irritation: Mild injection site redness and warmth are common. Usually transient.

Systemic doses: High systemic doses in animal models show cytotoxicity against mammalian cells (the mechanism is non-selective membrane disruption). Research doses are well below this threshold.

No FDA approval: Research compound. Phase II clinical investigation ongoing for specific indications.


References

  • [1]Hancock RE, Sahl HG. "Antimicrobial and host-defense peptides as new anti-infective therapeutic strategies." Nat Biotechnol. 2006;24(12):1551-1557.
  • [2]Zanetti M. "Cathelicidins, multifunctional peptides of the innate immunity." J Leukoc Biol. 2004;75(1):39-48.
  • [3]Steinstraesser L, et al. "Host defense peptides in wound healing." Mol Med. 2008;14(7-8):528-537.
  • [4]Lande R, et al. "Plasmacytoid dendritic cells sense self-DNA coupled with antimicrobial peptide." Nature. 2007;449(7162):564-569.
Key Terms
Reconstitution is the process of dissolving lyophilized (freeze-dried) peptide powder with a sterile diluent to create a…
Bacteriostatic water (BAC water) is sterile water for injection containing 0.9% benzyl alcohol as a preservative. It is …
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Verified Scientific Data Last audited:
Data Sources & External References
CAS Registry: 154947-66-7  ·  Molecular Formula: C205H340N60O53S  ·  Source: peer-reviewed literature  ·  Domain: ascendpeptide.org
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